In electrochemistry, the nernst equation is an equation that relates the reduction potential of an. Understanding the nernst equation and other electrochemical concepts. As shown in the example below, in the limit of an in. G, is also related to spontaneity of a reaction, therefore. Nernst equation is a general equation that relates the gibbs free energy and cell potential in electrochemistry. T temperature kelvin, which is generally 25 c 298 k. G nernst equation the goal of this handout is to help you avoid taking notes during the lecture. E ooxidation when o e o is positive, the reaction is spontaneous. Nernst equation solutions page 2 of 2 2 the potential for a voltaic cell shown below is 0. E cell potential v under specific conditions e cell potential at standardstate conditions r ideal gas constant 8. The nernst equation enables the determination of cell potential under nonstandard conditions. For the love of physics walter lewin may 16, 2011 duration. Arredondo navarro kathia del rocio lopez carlon baltazar medina garcia cecilia sarai penuelas lugo narda azucena vazquez sarabia itzel carolina facilitador.
It was named after walther nernst, a german physical chemist who formulated. It takes into account the values of standard electrode potentials, temperature, activity and the reaction quotient for the calculation of cell potential. An easy experimental approach for students francisco j. It is very helpful in determining cell potential, equilibrium constant etc. The nernst equation calculates the equilibrium potential also referred to as the nernst potential for an ion based on the charge on the ion i. Oli modern chemistry 2 video course problem set 32. Nernst equation can be used to find the cell potential at any moment in during a reaction or at conditions other than standardstate. A simple derivation of the nernst equation the goal of this handout is to help you avoid taking notes during the lecture.
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